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Intra- and Inter-chain polaron diffusion in regio-random polythiophene studied by muon spin relaxation

Intra- and Inter-chain polaron diffusion in regio-random polythiophene studied by muon spin relaxation
Risdiana, Fitrilawati, R. Hidayat, A. A. Nugroho, R. E. Siregar, M. O. Tjia, I. Watanabe
Universitas Padjadjaran, Physica B 405 (2010) S381–S383, ISSN: 0921-4526, journal homepage: www.elsevier.com/locate/physb
Bahasa Inggris
Universitas Padjadjaran, Physica B 405 (2010) S381–S383, ISSN: 0921-4526, journal homepage: www.elsevier.com/locate/physb
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Longitudinal Field (LF) muon-spin-relaxation measurements have been performed for polythiophene based polymers of regio-random poly(3-hexylthiophene-2,5-diyl) to elucidate the intra- and interchain hopping mechanisms. The LF dependent muon-spin depolarization rate indicates the occurrence of pronounced shift in the relative dominance of charge transport mechanism from intra-chain diffusion to inter-chain diffusion at 50 K which is higher than the 25 K observed previously for the regioregular case.

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