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Fluorescein Analogues as Photoremovable Protecting Groups Absorbing at ~520 nm

JudulFluorescein Analogues as Photoremovable Protecting Groups Absorbing at ~520 nm
PenulisPeter Sebej, Jurgen Wintner, Pavel Muller, Tomas Slanina, Jamaludin Al Anshori, Lovely Angel Panamparambil Antony, Petr Klan, Jakob Wirz
PenerbitUniversitas Padjadjaran, The Journal of Organic Chemistry 2012, dx.doi.org/10.1021/jo301455n
BahasaBahasa Inggris
Hak CiptaUniversitas Padjadjaran, The Journal of Organic Chemistry 2012, dx.doi.org/10.1021/jo301455n
Kata KunciPhotoremovable Protecting

A new photoremovable protecting group, (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl (1), with a molar absorption coe?cient e of ~4 × 104 m-1 cm-1 at ~520 nm for the release of carboxylates or phosphates is reported. Three derivatives of 1 (diethyl phosphate, acetate, and bromide) were isolated as complexes with DDQ and shown to release the ligands with quantum yields < 2.4% in aqueous solution.

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